Forgetful scientists’ breakthrough could deliver week-long Apple Watch battery life

“Today’s lithium-ion batteries typically rely on graphite anodes to offer a long lifespan. Rechargeable battery performance declines and eventually falls off a cliff (becomes unusable) due to those anodes repeatedly expanding and contracting as lithium ions migrate during the cycle of charging and discharge,” Matthew Humphries reports for Geek. “Lithium compounds build up on the electrodes during this process then break off during the expansion and contraction. This exposes the surface of the electrode and over time decomposes it to the point of failure.”

“A better alternative to using graphite for the anodes would be aluminum, but aluminum expands and contracts too much during each cycle. If scientists could stop that happening, we’d have much better performing batteries,” Humphries reports. “Dr Wang Changan of Tsinghua University and Dr Li Ju of MIT have been working together to stop the oxide coating that forms on the surface of aluminum nanoparticles when it is exposed to air. Their idea was to soak the nanoparticles in a sulfuric acid and titanium oxysuplphate mix, which would dissolve the aluminum oxide and replace it with titanium oxide.”

“Achieving the new outer coating required a set time of soaking. The accident occurred when Wang and Li forgot to remove one batch of the nanoparticles from the soaking process,” Humphries reports. “That batch ended up soaking for several hours longer than intended with the result being the sulfuric acid and titanium oxysulfate mix leaked into the 50nm nanoparticles and dissolved some of the aluminum inside. What this left was a nanoparticle with a 4nm outer shell of titanium hydroxide and an inner 30nm ‘yolk’ of aluminum… The extra long soak meant the anodes did not expand and contract, in fact they created a battery that over 500 charge/discharge cycles retained up to four-times the capacity of the equivalent graphite anode batteries. These batteries last considerably longer in terms of usable lifespan and, according to MIT, can hold up to three-times the energy.”

Read more in the full article here.

MacDailyNews Take: This reminds us of biologist Alexander Fleming who took a summer vacation from work in the lab investigating staphylococci. Upon his return on Sept. 3, 1928, as the story goes, Fleming found a strange fungus on a culture he had left in his lab — a fungus that had killed off all surrounding bacteria in the culture. Modern medicine was never the same after the discovery of Penicillin.

[Attribution: Cult of Mac. Thanks to MacDailyNews Reader “Fred Mertz” for the heads up.]

21 Comments

    1. Google BioSolar, they have done nearly the same thing with different materials and announced it last fall. They are claiming twice the capacity at one quarter the cost and say they can be in production by the end of this year. Don’t any of these people in the industry know how to put a Google Alert on “Battery Breakthrough”?

    1. I have discovered time travel and will show it to you now. By the time you have finished reading this, you will be in the future. Reverse time travel is still a dream.

  1. That’s it. From now on I am going to soak my aluminum in titanium acidic oxide, much longer. I will let you know the results.

    I have several batches in the fridge. I will go a whole week in one batch, with a low grade version. I think a slower process will have a more uniform structure and better results. The plan is a permanent battery that will last the lifetime of an iPhone, while charging once a month.

    However I have another change. The anode is not simply a core of aluminum. It’s copper, wrapped in aluminum.

    Wouldn’t it be ironic if my stupid snark actually worked, but because it’s a snark it’s completely ignored.

  2. As much as I like these stories, we have seen a half dozen research projects announce “breakthrough” in LiON battery life over the last 2 years.

    New technology also offers new ways for failure, so long life cycle testing and amelioration techniques. It is not easy.

    1. Post-It note glue ruined the accident story. Everyone reports positive results from accidents, and then no one else can reproduce it. It’s like cold fusion all over again.

      We will get there, but batteries are like CPUs with tiny little steps in improvement, with years and years of practice.

      There is no ahah moment, because it’s so complicated.

      Whatever happened to gallium arsenide anodes? Oh yeah, rarer than gold, not really a great solution.

  3. Never under estimate the powers of serendipity and sloppy science to reveal the splendors of the natural world.

    Dr Li: You left the batch soaking in solution longer than planned? In violation of standard procedures, protocols, and experimental design?
    Dr Wang: Yes.
    Dr Li: You moron!
    Dr Wang: The results were fantastic.
    Dr Li: Brilliant!
    Dr Wang: Alchemy is a blast!
    Dr Li: Let’s go f*ck something up and see what happens!

  4. I’m reminded of Brian Eno and Peter Schmidt’s Oblique Strategy cards. They’re used as an aid to creativity. They introduce an element of chaos or ‘Dada’ from an artist’s perspective.

    Seeing as we humans never know everything about anything, tossing creativity into science experiments is clearly useful (within reason).

    One of my very favorite recent bits of ridiculous science was the theorizing over ‘coral bleaching’ whereby coral animals would luff off their calcium carbonate skeleton base and float away dead. This phenomenon has left inconceivably vast stretches of coral reefs as barren as any desert.

    Initially, as in for DECADES, dimwit scienterrificists assumed it was due to The Greenhouse Effect and heating of the oceans. They paid no attention to the fact that the temperature of the ocean had been fluctuating up and down for literally billions of years. The fact that coral require use calcium carbonate precipitation didn’t penetrate their skulls. Nor did the continue equilibrium between carbon dioxide and carbonic acid, which is also affected by The Greenhouse Effect. Then recently the DUH Factor hit home and they realized that the oceans are being dramatically acidified, both by CO2 changing to carbonic acid AND from our incessant human self-destructive imperative to dumping our waste into where we live, planet Earth. THUS the death of coral. – – Perhaps having a card in the scientist’s oblique strategies deck labeled “pH” would have awoken the sleeping bad scientists. 🙄

    1. Oh and another ongoing bad science problem of the moment: Bee colony collapse disorder. Today’s melittologists apparently can’t handle multi-factor pathology. We already know all the factors that make the bees go nuts and fly off to die. But it’s just too complicated to deal with, apparently. Also, the horror corporations who have a vested interest in selling deadly insecticides want their money, not pollination of the world’s agriculture. And what these same clueless turds find a way to make money off our inability to pollinate crops without paying cash to the corporate parasites. Too predictable.

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